Poll Res. 41 (3) : 1056-1061 (2022)
Copyright © EM International
ISSN 0257–8050
DOI No.: http://doi.org/10.53550/PR.2022.v41i03.043
BIOSORPTION OF METHYLENE BLUE DYE FROM WASTEWATER
USING MODIFIED CHICKPEA HUSK AS AN ADSORBENT
SONIA RANI
1
, JYOTI RANI
1
, ANITA SINGH
1
, NARESH KUMAR
2
, SUDESH CHAUDHARY
1
*
1
Centre of Excellence for Energy and Environmental Studies, DCRUST,
Murthal, 131 039, Haryana, India
2
Government College for Women, Sonepat 131 001, Haryana, India
(Received 1 February, 2022; Accepted 4 March, 2022)
ABSTRACT
The purpose of this study was to extract activated carbons by chemical activation from chickpea
husks (H
2
SO
4
) and to investigate the adsorbent potential for removing dye from aqueous solutions.
SEM and FTIR techniques were initially defined as adsorbent. The experimental data were
evaluated to optimize the initial ion concentration, pH, contact time and adsorbent dose of the
different parameters. Various kinetic models and isotherm adsorption were used to illustrate the
adsorbent’s proper mechanism and performance. Langmuir adsorption isotherm found to have the
maximum adsorption potential of 200 mg/g.
KEY WORDS: Adsorption isotherms, Kinetics, Optimization, Chickpea husk.
INTRODUCTION
Dyes have for quite some time been utilized in the
dyeing, paper ventures; printing, materials, plastics,
cowhide, beautifiers, pharmaceuticals and agri-
nourishment businesses, yet the effluents released
by these enterprises represent certain dangers and
ecological issues (Hassaan et al., 2017). These
businesses have demonstrated a noteworthy
increment in the utilization of engineered colors as a
shading material. Since dyes have a manufactured
inception and complex sweet-smelling atomic
structures, they are dormant and hard to biodegrade
when released into waste streams (Kumar et al.,
2011). The expulsion of engineered dyes is of
extraordinary worry, since certain dye and their
debasement items might be cancer-causing agents
and poisonous and, therefore, their treatment can’t
rely upon biodegradation alone. The precious
methylene blue dye has been considered due to its
known solid adsorption onto solids, and it regularly
fills as a model compound for evacuating natural
contaminants and colored substances from fluid
arrangements (Hameed et al., 2007).
Numerous physico-chemical strategies have been
tried, yet just that of adsorption was viewed as
better than different procedures (Subramaniam et al.,
2015). Adsorption procedure is an appropriate
method for inorganic and natural contaminations
expulsion from wastewater, as a result of the
noteworthy preferences like ease, accessibility,
gainfulness, simplicity of activity, proficiency, and
adequacy than different strategies. This procedure is
anything but difficult to work and similarly
compelling in the evacuation of dangerous
contaminations, even at low fixations (Uddin, 2017).
Adsorption is ordinarily a surface marvel, its
exhibition being emphatically identified with the
interesting properties of explicitly structured sorbent
material. Adsorption procedure can be a physical
adsorption which include just moderately powerless
intermolecular powers, and chemisorptions which
include the development of a synthetic security
between the adsorbate particle and the outside of
the adsorbent (Sintayehu et al., 2016). In the present
study, we are investigating adsorption capacity of
activated chickpea husk (Cicer arientum) to eliminate
methylene blue dye from aqueous medium.
Chickpea husk is an agricultural waste produced
from husking mill.