Vol.:(0123456789) 1 3
Applied Nanoscience
https://doi.org/10.1007/s13204-018-0682-3
ORIGINAL ARTICLE
Silver nanoparticles: green synthesis using Phoenix dactylifera
fruit extract, characterization, and anti‑oxidant and anti‑microbial
activities
Anas Ejaz Shaikh
1
· Kshitij Vasant Satardekar
2
· Rummana Rehman Khan
3
· Nanda Amit Tarte
4
·
Siddhivinayak Satyasandha Barve
5
Received: 8 October 2017 / Accepted: 12 February 2018
© Springer-Verlag GmbH Germany, part of Springer Nature 2018
Abstract
Hydro-alcoholic (2:8 v/v) extract of the pulp of Phoenix dactylifera fruit pulp obtained using Soxhlet extraction (70 °C, 6 h)
was found to contain alkaloids, sterols, tannins, favonoids, cardiac glycosides, proteins, and carbohydrates. An aqueous solu-
tion (20% v/v) of the extract led to the synthesis of silver nanoparticles (AgNPs) from 0.01 M AgNO
3
solution as confrmed
by the surface plasmon resonance at 445 nm determined using UV–visible spectroscopy after 24 h. The synthesized AgNPs
were found to be mostly spherical and complexed with phytochemicals from the extract. The size of AgNPs ranged from
12.2–140.2 nm with mean diameter of 47.0 nm as characterized by scanning electron microscopy (SEM). The elemental
composition of the AgNPs complexed with the phytochemicals was found to be 80.49% silver (Ag), 15.21% carbon (C), and
4.30% oxygen (O) on a weight basis by energy-dispersive spectroscopy (EDS). Using the α,α-diphenyl-β-picrylhydrazyl
(DPPH) assay, an anti-oxidant activity of 89.15% for 1 µg L
−1
ultrasonically homogenized ethanolic solution of complexed
AgNPs was obtained (equivalent to 0.20 mg mL
−1
gallic acid solution), while methanolic solution of plant extract possessed
an EC
50
value of 3.45% (v/v) (equivalent to 0.11 mg mL
−1
gallic acid solution). The plant-nanosilver broth was also found
to possess efective anti-microbial activity against Escherichia coli ATCC 8739, Staphylococcus aureus ATCC 6538, and
Candida albicans ATCC 10231 as assessed by the disc difusion assay. However, the plant extract showed negligible anti-
microbial activity.
Keywords Silver nanoparticles · Green synthesis · Phoenix dactylifera · Anti-oxidant · Anti-microbial
Electronic supplementary material The online version of this
article (https://doi.org/10.1007/s13204-018-0682-3) contains
supplementary material, which is available to authorized users.
* Anas Ejaz Shaikh
anass1250@gmail.com
Kshitij Vasant Satardekar
kvsatardekar@gmail.com
Rummana Rehman Khan
micro@kelkarresearchcentre.org
Nanda Amit Tarte
drnanda.tarte@gmail.com
Siddhivinayak Satyasandha Barve
drssbarve@gmail.com
1
Department of Food Engineering and Technology, Institute
of Chemical Technology, Mumbai 400019, Maharashtra,
India
2
Animal Biotechnology and Biochemistry Division,
Kelkar Education Trust’s Scientifc Research Centre,
Mumbai 400081, Maharashtra, India
3
Microbiology and Plant Biotechnology Division,
Kelkar Education Trust’s Scientifc Research Centre,
Mumbai 400081, Maharashtra, India
4
Department of Biotechnology, Kelkar Education Trust’s
V. G. Vaze College of Arts, Science and Commerce,
Mumbai 400081, Maharashtra, India
5
Department of Botany, Kelkar Education Trust’s V. G. Vaze
College of Arts, Science and Commerce, Mumbai 400081,
Maharashtra, India