Vol. 7(10), pp. 197-202, November, 2013
DOI: 10.5897/AJBR12.073
ISSN 1996-0778 ©2013 AcademicJournals
http://www.academicjournals.org/AJBR
African Journal of Biochemistry Research
Full Length Research Paper
Production of tannase and gallic acid by Aspergillus
tamarii in submerged and solid state cultures
Andrea Miura da Costa
1
, Cristina Giatti Marques de Souza
2
, Adelar Bracht
2
, Marina Kimiko
Kadowaki
3
, Aline Cristine da Silva de Souza
2
, Roselene Ferreira Oliveira
2
and
Rosane Marina Peralta
2
*
1
State University of Santa Cruz, Ilhéus, BA, Brazil.
2
State University of Maringá, Maringá, PR, Brazil.
3
State University of West Paraná, Cascavel, PR, Brazil.
Accepted September 17, 2013
The hydrolytic enzyme, tannase and the antioxidant phenolic compound, gallic acid are useful in many
biotechnological processes especially in food and pharmaceutical areas. The purpose of this study was
to evaluate the production of tannase and gallic acid by Aspergillus tamarii developed in submerged
and solid state cultures using tannic acid as substrate. In submerged cultures, maximal tannase activity
(20,400 ± 2,900 U/L) was obtained after 2 days of cultivation using 2% tannic acid as substrate. In solid
state cultivation using polyurethane foam as inert support, maximal tannase activity was obtained after
4 days of cultivation in 15% tannic acid cultures (25,470 ± 1,600 U/L). In both types of cultures, high
accumulation of gallic acid was found in the two day-culture filtrates, 0.36±0.05 and 0.67±0.08 g of gallic
acid per g of tannic acid, in submerged and solid state cultures, respectively. The accumulation of gallic
acid in the cultures is, however, a transitory phenomenon, considering that the fungus slowly absorbs
and metabolizes gallic acid.
Key words: Aspergillus tamari, gallic acid, inert support, solid-state cultures, submerged cultures, tannase.
INTRODUCTION
Tannin acyl hydrolase (EC 3.1.1.20), commonly called
tannase, catalyzes the hydrolysis of ester bonds into
hydrolysable tannins such as tannic acid, thereby
releasing glucose and gallic acid (Aguilar et al., 2007;
Bhat et al., 1998; Lekha and Lonsane, 1997). The
chemical formula for commercial tannic acid is often
given as C
76
H
52
O
46,
which corresponds to decagalloyl
glucose, but it is a mixture of polygalloyl glucoses or
polygalloyl quinic acid esters with the number of galloyl
moieties per molecule ranging from 2 to 12, depending
on the plant source used to extract the tannic acid.
Tannase is an important enzyme used in the
pharmaceutical and food industries and also for analytical
and developmental purposes (Aguilar et al., 2007).
Tannases contribute to removal of the undesirable effects
of tannins in the elaboration of instantaneous tea. They
also act as clarifying agents in some wines, juices of
fruits and in refreshing drinks with coffee flavour (Boadi
and Neufeld, 2001; Belmares et al., 2004). Other
important application of tannase in the food industry is its
use in the production of gallic acid, a substrate for the
chemical synthesis of pyrogallol, which is used in a
variety of industrial sector, such as a developer in
photography, to make colloidal solutions of metals, as a
mordant for wool, for staining leather, in process
engraving, in the manufacture of various dyes, and in the
dyeing of fur, hair, etc (Cruz-Hernandez et al., 2005).
Gallic acid is also precursor in the enzymatic synthesis of
*Corresponding author. E-mail: rmperalta@uem.br or rosanemperalta@gmail.com.