Available online at www.sciencedirect.com
ScienceDirect
Materials Today: Proceedings 16 (2019) 1686–1691 www.materialstoday.com/proceedings
2214-7853 © 2019 Elsevier Ltd. All rights reserved.
Selection and/or Peer-review under responsibility of Biomedical and Advanced Materials (Biocam 2017).
Bio-CAM 2017
Corrosion analysis of hydroxyapatite coated magnesium in
simulated body fluid (SBF), phosphate buffered saline (PBS), and
Ringer's solution
Mohd Amin Farhan Zaludin
a,
*, Zul Azhar Zahid Jamal
a
, Mohd Nazree Derman
a
,
Mohd Zaheruddin Kasmuin
a
a
Centre of Excellence for Frontier Materials Research, School of Materials Engineering, Universiti Malaysia Perlis (UniMAP), No. 66- 68, Blok
B, Taman Pertiwi Indah, Seriab, 01000, Kangar, Perlis, Malaysia.
Abstract
Magnesium, Mg is well known as a degradable biomaterials and the degradability is governed by corrosion
process.. In order for Mg to be bioactive, hydroxyapatite, HA coating seems to be the best candidate for Mg. The
main objective of the current work is to assess the corrosion behaviour of HA coated Mg inside different corrosion
media (SBF, PBS, and Ringers). The coated samples were prepared via two steps chemical conversion coating,
which is the primary step were by phosphating and followed by secondary alkaline treatment. Corrosion analyses
were conducted by using potentiodynamic polarization and the effect of different corrosion media is evaluated from
microstructural and phase analysis perspective. It is suggested that the corrosion properties of HA coated Mg is
strongly influenced by ionic concentrations of the corrosion testing solutions. It is found that the corrosiveness of the
solution media (from less to the most corrosive) is given by PBS ˂ SBF ˂ Ringers. The Cl
-
concentrations strongly
affect the corrosion rate inside the tested solutions. However, presence of other ions inside the tested solutions such
as HCO
3-
, HPO
4
2-
, SO
4
2-
helps inhibits the attack of aggressive Cl
-
ions.
© 2019 Elsevier Ltd. All rights reserved.
Selection and/or Peer-review under responsibility of Biomedical and Advanced Materials (Biocam 2017)
Keywords: Magnesium; Hydroxyapatite coating; SBF; PBS; Ringer's
* Corresponding author. Tel.:+6019-4579117.
E-mail address: aminzaludin90@yahoo.com