1 A kinetic study on the catalysis of KCl, K2SO4, and K2CO3 during oxy-biomass combustion Shuanghui Deng a , Xuebin Wang a, * , Jiaye Zhang a , Zihan Liu a , Hrvoje Mikulčić b , Milan Vujanović b , Houzhang Tan a , Neven Duić b a MOE Key Laboratory of Thermo-Fluid Science and Engineering, Xi’an Jiaotong University, Xi’an 710049, Shaanxi, China b Faculty of Mechanical Engineering and Naval Architecture, University of Zagreb, Zagreb 10000, Croatia E-mail: wxb005@mail.xjtu.edu.cn ABSTRACT Biomass combustion under the oxy-fuel conditions (Oxy-biomass combustion) is one of the approaches achieving negative CO2 emissions. KCl, K2CO3 and K2SO4, as the major potassium species in biomass ash, can catalytically affect biomass combustion. In this paper, the catalysis of the representative potassium salts on oxy-biomass combustion was studied using a thermogravimetric analyser (TGA). Effects of potassium salt types (KCl, K2CO3 and K2SO4), loading concentrations (0, 1, 3, 5, 8 wt.%), replacing N2 by CO2, and O2 concentrations (5, 20, 30 vol.%) on the catalysis degree were discussed. The comparison between TG-DTG curves of biomass combustion before and after water washing in both the 20%O2/80%N2 and 20%O2/80%CO2 atmospheres indicates that the water-soluble minerals in biomass play a role in promoting the devolatilization and accelerating the char-oxidation; and the replacement of N2 by CO2 inhibits the devolatilization and char-oxidation processes during oxy-biomass combustion. In the devolatilization stage, the catalysis degree of potassium monotonously increases with the increase of potassium salt loaded concentration. The catalysis degree order of the studied potassium salts is K2CO3 > KCl > K2SO4. In the char-oxidation stage, with the increase of loading concentration the three kinds of potassium salts present inconsistent change tendencies of the catalysis degree. In the studied loading concentrations from 0 to 8 wt.%, there is an optimal loading concentration for KCl and K2CO3, at 3 wt.% and 5 wt.%, respectively; while for K2SO4, the catalysis degree on char-oxidation monotonically increases with