LETTER TO THE EDITOR
COMMENTS ON ‘‘A FAST METHOD FOR DETERMINING SOIL
PARTICLE SIZE DISTRIBUTION USING A LASER INSTRUMENT’’
BY F. J. ARRIAGA, B. LOWERY, AND D. W. MAYS.
SOIL SCI. 171:663–674 (2006)
Particle size distribution (PSD) is one of the
most fundamental physical properties of a soil,
strongly affecting many physical and chemical soil
properties. Commonly used methods for PSD
determination, such as sieving and procedures
based on sedimentation (e.g., the pipette and
hydrometer methods), are both time and labor
consuming. Therefore, the attempt to develop a
fast and simple method for PSD determination,
such as that proposed in the current article with
the aid of a laser diffraction instrument (LD), is
most welcome and should be encouraged.
However, the authors have set themselves
an additional goal, namely to relate and match
PSD data obtained from the LD to those from
the combined sieve-pipette method. We main-
tain that such an approach, which attempts to
convert LD-derived volume percent of a given
size fraction to a pipette-derived mass percent
(or vice versa), is inaccurate and should not be
advocated, because it may possibly mislead
readers, especially those unfamiliar with the
finer details of the various methods used for
PSD analyses. We base our contention on the
following arguments.
NONSPHERICITY OF SOIL PARTICLES
A major problem associated with the accurate
description of the PSD of soil material is the fact
that soil particles are irregularly shaped particles.
Hence, for simplicity and ease of analysis, particle
size in soils is presented as an Bequivalent^
spherical particle, which allows the use of a single
length (apparent diameter) as the descriptor. The
impact of applying this simplification on the
obtained PSD from different methods has been
discussed in detail by Eshel et al. (2004) and is
summarized as follows. In the case of sieving, the
net outcome of the nonsphericity of soil particles
results in the underestimation of the sand size
fraction when wet sieving and sedimentation are
combined for the determination of PSD. In
sedimentation-based techniques (e.g., pipette),
the nonsphericity of the particles affects the
settling velocity, and the fine size fraction is,
therefore, overestimated. In the LD analysis, the
projected cross-sectional area of a nonspherical
particle is larger than that of a sphere with an
equal volume (Jonasz, 1991), which leads to a
shift of the PSD toward its coarser fractions.
It is evident from the above that the afore-
mentioned simplification, arising from the non-
sphericity of soil particles, leads to the
dependence of the obtained PSD on the method
used for its determination (Matthews, 1991).
This dependence casts severe doubts as to the
validity of the attempts to correlate PSD data
obtained by one method to those obtained by a
different method. Furthermore, it clearly indi-
cates that there is no Bexact^ method (as referred
to the pipette method by the authors in the
Conclusion section of the article) but that the
choice between methods depends simply on
the balance between the pros and cons of each.
REFRACTIVE INDEX
Use of the LD method for determining soil
PSD entails the employment of the Mie theory
model. The Mie theory requires, as an input
parameter, the refractive index (RI), which is a
complex number comprised of (i) a real part (n
r
),
which represents the change in the velocity of
light through the tested material compared with
the velocity of light in vacuum, and (ii) an
imaginary term (n
i
), which represents the trans-
parency and absorptivity of that material. The
RI is, therefore, not just a Bfitting parameter^
that can be manipulated to bring closer different
data sets, but a parameter of a physical meaning
413
0038-075X/07/17205-413–415 May 2007
Soil Science Vol. 172, No. 5
Copyright * 2007 by Lippincott Williams & Wilkins, Inc. Printed in U.S.A.
Copyr ight © Lippincott Williams & Wilkins. Unauthor iz ed reproduction of this article is prohibited.