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International Journal of Nanomedicine 2016:11 4299–4316
International Journal of Nanomedicine Dovepress
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systemic distribution of single-walled carbon
nanotubes in a novel model: alteration of
biochemical parameters, metabolic functions,
liver accumulation, and infammation in vivo
elisa Principi,
1,
* rossana
girardello,
2,
* antonino
Bruno,
1,
* Isabella Manni,
3
elisabetta gini,
2
ari anna
Pagani,
1
annalisa grimaldi,
2
Federico Ivaldi,
4
Terenzio
congiu,
5
Daniela De
stefano,
1
giulia Pia ggio,
3
Magda de eguil eor,
2
Douglas M Noonan,
1,2
adri ana albini
1
1
Vascular Biology and angiogenesis,
scientific and Technology Pole,
Irccs MultiMedi ca, Milano,
2
Department of Biotechnology
and life sciences, University of
Insubria, Varese,
3
Department of
research, advanced Diagnosis and
Innovation, regina el ena National
cancer Institute, rome,
4
Department
of Neuroscience, Ophthalmology
and genetics, University of genoa,
genoa,
5
Department of surgical and
Morphological sciences, University of
Insubria, Varese, Italy
*These authors contributed equally
to this work
Abstract: The increasing use of carbon nanotubes (CNTs) in several industrial applications
raises concerns on their potential toxicity due to factors such as tissue penetrance, small dimen-
sions, and biopersistence. Using an in vivo model for CNT environmental exposure, mimicking
CNT exposition at the workplace, we previously found that CNTs rapidly enter and disseminate
in the organism, initially accumulating in the lungs and brain and later reaching the liver and
kidneys via the bloodstream in CD1 mice. Here, we monitored and traced the accumulation of
single-walled CNTs (SWCNTs), administered systemically in mice, in different organs and the
subsequent biological responses. Using the novel in vivo model, MITO-Luc bioluminescence
reporter mice, we found that SWCNTs induce systemic cell proliferation, indicating a dynamic
response of cells of both bone marrow and the immune system. We then examined metabolic
(water/food consumption and dejections), functional (serum enzymes), and morphological
(organs and tissues) alterations in CD1 mice treated with SWCNTs, using metabolic cages,
performing serum analyses, and applying histological, immunohistochemical, and ultrastruc-
tural (transmission electron microscopy) methods. We observed a transient accumulation of
SWCNTs in the lungs, spleen, and kidneys of CD1 mice exposed to SWCNTs. A dose- and
time-dependent accumulation was found in the liver, associated with increases in levels of
aspartate aminotransferase, alanine aminotransferase and bilirubinemia, which are metabolic
markers associated with liver damage. Our data suggest that hepatic accumulation of SWCNTs
associated with liver damage results in an M1 macrophage-driven inflammation.
Keywords: single-walled carbon nanotubes, nanotoxicity, metabolism, hepatic function,
inflammation, Kupffer cells, mouse models
Introduction
Given their unique chemical and physical properties, carbon nanotubes (CNTs)
represent a class of nanoparticles widely used in several industrial settings. Single-
walled CNTs (SWCNTs) are also of interest for their potential medical applications,
1
including in vivo delivery
2–4
of drugs,
5
proteins, peptides,
6–8
and nucleic acids
8
for gene
transfer
9
or gene silencing.
6
In oncology, experimental studies have been focused on
SWCNTs as a new tool to target tumor cells
10
for antineoplastic treatment of tumor
angiogenesis and in vivo tumor imaging.
11
The small diameter, the relatively long
length, and the biopersistence of CNTs have been linked to the structure of asbestos,
suggesting extensive concerns on potential pulmonary health hazards.
12–17
CNT tissue
accumulation, stability over long periods, final fate, and toxicological impact on health
correspondence: Douglas M Noonan
Scientifc and Technology Pole, IRCCS
Multimedica, Via g. Fantoli 16/15,
Milano 20138, Italy
Tel +39 025 540 6532
Fax +39 332 21 7609
email douglas.noonan@uninsubria.it
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