Vol.:(0123456789) 1 3
Molecular Biology Reports
https://doi.org/10.1007/s11033-019-04689-8
ORIGINAL ARTICLE
Phytosterols and triterpenes from Morinda lucida Benth. exhibit
binding tendency against class I HDAC and HDAC7 isoforms
Ahmed Adebayo Ishola
1
· Kayode Ezekiel Adewole
2
Received: 11 December 2018 / Accepted: 7 February 2019
© Springer Nature B.V. 2019
Abstract
The important role of histone deacetylases (HDACs) in the development of cancer has been demonstrated by various studies.
Thus targeting HDACs with inhibitors is a major focus in anticancer drug research. Although few synthetic HDAC inhibitors
(HDIs) have been approved for cancer treatment, they have signifcant undesirable side efects. Therefore emphases have
been placed on natural HDIs as substitutes for the synthetic ones. In a bid to identify more HDIs, this study evaluated the
binding tendency of compounds derived from Morinda lucida Benth. towards selected HDACs for the discovery of potent
HDIs as potential candidates for anticancer therapeutics, based on the report of anticancer potentials of Morinda lucida-
derived extracts and compounds. Givinostat and 49 Morinda-lucida derived compounds were docked against selected HDAC
isoforms using AutodockVina, while binding interactions were viewed with Discovery Studio Visualizer, BIOVIA, 2016.
Druglikeness and Absorption–Distribution–Metabolism–Excretion (ADME) parameters of the top 7 compounds were evalu-
ated using the Swiss online ADME web tool. The results revealed that out of the 49 compounds, 3 phytosterols (campesterol,
cycloartenol, and stigmasterol) and 2 triterpenes (oleanolic acid and ursolic acid) exhibited high HDAC inhibitory activity
compared to givinostat. These 5 compounds also fulfll oral drugability of Lipinski rule of fve. Morinda lucida-derived
phytosterols and triterpenes show high binding tendency towards the selected HDACs and exhibited good drugability char-
acteristics and are therefore good candidates for further studies in the search for therapies against abnormalities linked with
over-activity of HDACs.
Keywords HDACs · Morinda lucida · Anticancer · Phytosterols · Triterpenes
Introduction
Histone deacetylases (HDACs) are target enzymes in the
epigenetic modulation of genomic activity and may be
exploited in the treatment of many diseases, including cancer
[1]. Cancer is currently one of the serious health challenges
facing the world, killing about 9 million people in 2015 [2].
It is the cause of 1 in every 6 deaths reported globally; out
of which low and middle-income nations account for about
70% [2]. Cancer is caused by altered cell chemistry upsetting
the delicate control of cell cycle, angiogenesis, apoptosis
and other vital cellular processes [3, 4]. It has now been
confrmed that apart from genetic changes, progression of
cancer could also be caused by altered epigenetic processes
without modifcation in DNA sequence [5]. These epige-
netic processes include methylation of DNA, modifcation of
histone protein and non-coding RNA deregulation [5]. The
important role of epigenetic mechanisms in the development
of cancer has been demonstrated by various studies, and his-
tone acetylation is one of such key epigenetic processes [6].
Histone acetylation is maintained in active balance by his-
tone acetyl transferases and histone deacetylases [7]. HDACs
catalyze the removal of acetyl group from N-terminal lysine
side chain of histone and non-histone proteins. This revers-
ible process is one of the most common events in post-trans-
lational modifcations. Aberrant protein acetylation has been
linked to cancer while abnormal expression of HDACs has
been established in various cancer types [8]. The role of
HDACs in this important epigenetic process has therefore
made them promising targets of anticancer drug discovery
* Kayode Ezekiel Adewole
kayowolemi@gmail.com
1
Department of Biochemistry, Faculty of Life Sciences,
University of Ilorin, Ilorin, Nigeria
2
Biochemistry Unit, Department of Chemical Sciences,
Faculty of Natural Sciences, Ajayi Crowther University Oyo,
Oyo, Oyo State, Nigeria