32 Copyright © 2019, IGI Global. Copying or distributing in print or electronic forms without written permission of IGI Global is prohibited. Chapter 3 DOI: 10.4018/978-1-5225-7888-8.ch003 ABSTRACT In fragile environments, such as the Western Amazon, there is a latent concern related to solid waste, deserving emphasis from the conceptual point of view, where the origin of sustainability becomes the emergency that forces the behavior through recycling seeking the reduction and absence of residues. Epistemology has as its function, among others, to defne what provides conditions for examining rela- tions between facts and theories. The question is, What does conceptual aspect contribute to awareness and improvement to the relation of capital, labor, and society? Apply the Theory U as argumentation in this relation. The general and main objective of this chapter is to deal with the epistemological aspect of sustainability against the capital, labor, and society based on the Theory U. As a result, the conceptual aspect contributes to awareness and improvement of the relation of capital, labor, and society consider- ing the discourses treated in fragile environments in the Western Amazon. Epistemological Character of Sustainability and Value Creation: Study in the Western Amazon Jacira Lima da Graça Federal University of Rondônia (GEITEC-UNIR), Brazil Flavio de São Pedro Filho Federal University of Rondônia (GEITEC-UNIR), Brazil Maria José Aguilar Madeira University of Beira Interior (UBI), Portugal Antonio Vicente da Graça Filho Pontifcal Catholic University of São Paulo (PUC), Brazil Marcelo Augusto Mendes Barbosa University Center São Lucas (UNISL), Brazil Izabel Cristina da Silva Federal University of Rondônia (GEITEC-UNIR), Brazil