Part load operation of a solid oxide electrolysis
system for integration with renewable energy
sources
Javier Sanz-Bermejo
a
, Javier Mu
~
noz-Ant
on
b
, Jos
e Gonzalez-Aguilar
a
,
Manuel Romero
a,*
a
IMDEA Energy Institute, Avda. Ram on de la Sagra, 3, 28935, M ostoles, Spain
b
GIT - Technical University of Madrid, Jos e Guti errez Abascal 2, 28006, Madrid, Spain
article info
Article history:
Received 9 January 2015
Received in revised form
11 March 2015
Accepted 11 April 2015
Available online xxx
Keywords:
Hydrogen production
Steam electrolysis
SOEC
Part load operation
Operational strategies
Area specific resistance
abstract
100 % carbon-free energy economy might require the interconnection between electricity,
gas and transport fuel energy systems and the development of large-scale energy storage
systems. All of these can be achieved through electrolysis plants. These plants can produce
hydrogen during renewable electricity surplus periods, which can be fed into the natural
gas network or sold as transport fuel. In this study a complete model of a solid-oxide
electrolysis process has been implemented in order to optimize the design of the process
and its operation at part load. Different thermodynamic cell operational modes (constant
cell inlet temperature vs. thermoneutral following point) and operational strategies (con-
stant steam conversion vs. constant flow rate) have been analysed. Additionally, three
different temperature-dependent area specific resistance equations have been imple-
mented in order to analyse the influence of the dependency of the ionic conductivity of the
electrolyte on temperature over the performance of the process.
As result of the analysis, it has been seen that the system is able to operate from 10 to
100 % power load improving the compatibility of solid-oxide electrolysis systems with high
transient renewable energy sources. The study reveals that the hydrogen production sys-
tem can achieve a very flat performance curve within the whole power load range, with
overall efficiencies between 91 % and 97 % vs. HHV. This is possible if at low power loads
the electrolyser is operated under constant steam conversion mode; whereas at high loads,
this is switched to constant flow rate mode. Finally, cells with high variation of area spe-
cific resistance with temperature suffers the lowest temperature variation along the power
load. This makes possible to increase the operational power range and might reduce
thermal stress increasing the lifespan of the cells.
Copyright © 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights
reserved.
* Corresponding author. Tel.: þ34 91 737 1120.
E-mail address: manuel.romero@imdea.org (M. Romero).
Available online at www.sciencedirect.com
ScienceDirect
journal homepage: www.elsevier.com/locate/he
international journal of hydrogen energy xxx (2015) 1 e13
http://dx.doi.org/10.1016/j.ijhydene.2015.04.059
0360-3199/Copyright © 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
Please cite this article in press as: Sanz-Bermejo J, et al., Part load operation of a solid oxide electrolysis system for integration
with renewable energy sources, International Journal of Hydrogen Energy (2015), http://dx.doi.org/10.1016/
j.ijhydene.2015.04.059