23
© 2016 Conscientia Beam. All Rights Reserved.
MODELING OF A TUBULAR FIXED-BED REACTOR FOR THE
PRODUCTION OF DIMETHYL ETHER USING ALUMINA CATALYST
Dagde, Kenneth Kekpugile
1
--- Harry, Uduak Sylvanus
2
1,2
Department of Chemical/Petrochemical Engineering, Rivers State University of Science and Technology, Port Harcourt, Nigeria
ABSTRACT
A model to predict the behavior of an adiabatic tubular fixed-bed reactor for the production of dimethyl
ether using alumina catalyst was developed. The steady state model incorporates the reaction rate kinetic
expression obtained from literature into the model equations. The models were integrated numerically
using Fourth-order Runge-Kutta method incorporated into a computer simulator (MATLAB 7.7 code).
Model predictions are compared with data obtained from the literature under the same operating conditions
and a good agreement is obtained with a variation ranging from 0.5% to 2.7%. The simulation results
show that the production of dimethyl ether is greatly affected by parameters such as temperature, and feed
flow rate with optimum yield of DME at a catalyst bed height of 2-4m at a temperature of 557 to 570K.
Keywords: Fixed-bed reactor, Natural gas, Methanol dehydration, Modeling, Simulation, Dimethyl ether, Alumina
catalyst.
Contribution/ Originality
This study contributes in the existing literature by developing model equations that is used
in predicting/simulation of functional parameters for optimum yield of DME. Unlike other works
which assume isothermal condition, this study assumes an adiabatic condition and could be
adopted for simulation of industrial DME plant.
1. INTRODUCTION
Natural gas is used for DME production, and Nigeria is blessed with this raw material,
making DME usage in Nigeria a very attractive choice. With the use of DME as fuel for both
diesel engines and domestic use, pollution can be controlled to a very large extent because it does
not produce pollutants as compared to diesel fuels. Dimethyl ether (DME) is the simplest ether
having the chemical formula of CH
3
OCH
3
. DME is a colorless gas at an ambient condition; its
vapor pressure is about 0.6 MPa at 25
o
C, DME is easily to liquefied under low pressure [1]. Its
physical properties are similar to those of propane and butane, which are the principal
International Journal of Chemical and Process Engineering Research
2016 Vol. 3, No. 2, pp. 23-34
ISSN(e): 2313-0776
ISSN(p): 2313-2558
DOI: 10.18488/journal.65/2016.3.2/65.2.23.34
© 2016 Conscientia Beam. All Rights Reserved.