Electron. Mater. Lett., Vol. 9, No. 5 (2013), pp. 615-620
Red Upconversion Luminescence and Paramagnetism in Er/Yb Doped SnO
2
Shweta Sharma, Jyoti Shah, R.K. Kotnala, and Santa Chawla*
CSIR-National Physical Laboratory, Dr. K.S. Krishnan Road, New Delhi - 110012, India
(received date: 27 November 2012 / accepted date: 22 February 2013 / published date: 10 September 2013)
Red upconversion luminescence has been introduced in functional semiconductor SnO2 by doping rare earth
ions Er
3+
and Yb
3+
and using 980 nm diode laser as pump source. High temperature solid state reaction
leads to incorporation of trivalent lanthanide ions in SnO2. For high concentrations of lanthanide doping,
partial reduction of Sn
4+
to Sn
2+
occurs for charge compensation making the material system SnO2-SnO alloy.
Upconverting SnO2 exhibits paramagnetic characteristics with magnetization increasing with introduction of
trivalent rare earth ions Er
3+
/Yb
3+
.
Keywords: up conversion luminescence, semiconductor, rare earth, paramagnetism
1. INTRODUCTION
Rare earth (RE) doped multifunctional luminescent semi-
conductors is a promising new class of materials that can
have important applications in areas like solar cells,
[1]
optoelectronic devices,
[2]
biological systems
[3]
and drug
delivery. Frequency up conversion (UC) luminescence plays
an important role in infra red (IR) to visible spectrum
modification and such phosphors have been shown to
enhance efficiency of solar cells by harnessing otherwise
unutilized solar IR energy for photovoltaic conversion.
[4]
A
functional semiconductor like SnO
2
with wide band gap
(3.6 eV) holds special interest due to its novel properties and
applications such as transparent conducting electrode, gas
sensing, solar photovoltaic conversion, photo catalysis
etc.
[5-11]
. Because of such wide applicability, SnO
2
micro and
nano structures and their optical properties have been
reported extensively.
[12-17]
The present work endeavors to
introduce new properties in SnO
2
by doping with trivalent
rare earth ions Er
3+
and Yb
3+
- well known emitter and
sensitizer for UC luminescence. UC luminescence has been
reported mostly in insulating fluoride and oxide hosts doped
with rare earth emitters Er
3+
, Tm
3+
, Ho
3+
etc with Yb
3+
as
sensitizer due to its efficient resonant absorption of IR
(~980 nm) radiation and transfer to ladder like energy levels
of RE emitter.
[18,19]
The phenomenon of up conversion under
such excitation has been reported for YLiF
4
:Tm
3+
,Yb
3+
;
Y
2
O
2
S:Yb,Ho;
[20,21]
Y
2
O
3
: Er
3+
,Yb
3+
nanorods and Er
3+
,Yb
3+
codoped LaPO
4
nanocrystals;
[22,23]
NaYF
4
:Er
3+
,Yb
3+
core/
shell nanoparticles
[4]
; Y
2
O
3
, ZrO
2
, when doped with Er
3+
;
[18,19]
Tm
3+
/Er
3+
/Yb
3+
tri-doped CaF
2
phosphors with white light
emission,
[29]
ZrO
2
: Er
3+
, Yb
3+
nanocrystals with red (650 -
685 nm) and green UC emission (520 - 560 nm).
[24,25]
Blue,
green, and red UC emissions were observed in Er
3+
doped
ZnO nanocrystals annealed at different temperatures under
near-infrared light (808 nm) excitation.
[26]
Porous silicon
(PSL) also exhibits a strong visible luminescence under IR
radiation.
[27,28]
SnO
2
: Er
3+
has shown UC luminescence and
waveguide properties and has also shown applications in
optical amplifiers and electroluminescent devices.
[30]
The present study shows that rare earth lanthanide doping
in SnO
2
particles not only make them up convert IR light to
red, they also become paramagnetic thus making them bi-
functional UC fluorescent, magnetic semiconductor. A bi-
functional non toxic semiconductor such as trivalent RE
doped up conversion luminescent SnO
2
could have important
application in spintronics in addition to holding special
advantage for application in biological systems due to
negligible autofluorescence and photo bleaching with IR
excitation compared to down conversion phosphor nano-
particles (NP). The synthesis, structural, luminescence and
magnetic properties of SnO
2
doped with Er and Er,Yb ions
have been described.
2. EXPERIMENTAL PROCEDURE
2.1 Synthesis of undoped and doped SnO
2
particles by
Solid state reaction method
All the precursor materials have been used as obtained
without any further purification. For synthesis of undoped
SnO
2
nanoparticles by solid state reaction method commercial
Tin oxide (1 M) was weighed and packed in alumina boat
and fired at 1450°C in high temperature furnace for 3 hours
in air atmosphere. For synthesis of SnO
2
doped with erbium
(Er), Er
2
O
3
was used (2 mol. %) as substitutional dopant in
DOI: 10.1007/s13391-013-2230-3
*Corresponding author: santa@nplindia.org
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