Journal of Mechanical Engineering Vol SI 2 (1), 113-125, 2017
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ISSN 1823-5514, eISSN 2550-164X Received for review: 2016-12-07
© 2017 Faculty of Mechanical Engineering, Accepted for publication: 2017-01-20
Universiti Teknologi MARA (UiTM), Malaysia. Published: 2017-05-15
Bio-Recovery of Silver from
Simulated Silver Electroplating
Wastewater Using Palm (Elaeis
guineensis) Leaves Extract
Ahmad Arif
Junaidah Jai
Norashikin Ahmad Zamanhuri
Faculty of Chemical Engineering, Universiti Teknologi MARA (UiTM),
40450 Shah Alam, Malaysia
ABSTRACT
In this research, the role of an eco-friendly biomaterial, palm (Elaeis
guineensis) leaves extract as a reducing and stabilizing agent to recover
precious metal silver from simulated silver electroplating wastewater, was
studied. The phytochemical compounds present in the palm leaves extract,
which possesses antioxidant properties, were characterized according to
their functional groups and the parameters involved in affecting the silver
bio-recovery effectiveness were investigated. The studies found that major
types of phytochemical compounds that assist silver bio-recovery were
polyphenols, alcohols, carboxylic acid and reducing sugars. Meanwhile, the
parameters of reactant’s concentration ratio, acidity and metal impurities
were found to absolutely affect the silver bio-recovery effectiveness. The
characterization of the recovered suspended solid particles after the bio-
reduction process reveals that silver metals with high degree of crystallinity
were successfully recovered and in nano-sized.
Keywords: Palm Leaves Extract, Natural Antioxidant, Silver Wastewater,
Bio-Recovery, Silver Nanoparticles.
Introduction
Electroplating is the application of a metal coating onto a metallic or other
conducting surfaces by an electrochemical process [1]. This process however
could generate a lot of metal wastes mainly in rinsewater and spent
electroplating bath solution [2]. For common metals, it is still acceptable to