Phase control of electron population, absorption, and dispersion properties of a semiconductor quantum well J. F. Dynes* London Center for Nanotechnology, London WC1H 0AH, United Kingdom E. Paspalakis Materials Science Department, School of Natural Sciences, University of Patras, Patras 265 04, Greece Received 16 January 2006; revised manuscript received 25 April 2006; published 16 June 2006 We show that an asymmetric semiconductor quantum well that forms a three-level cascade configuration can be controlled by the relative phase of a laser field and its second harmonic. The electron population in the three subbands and the probe absorption/dispersion spectra are crucially phase dependent. As an example, electron inversion between the upper and lower subbands and change of the spectrum from absorption to gain is found by solely varying the relative phase of the two fields. DOI: 10.1103/PhysRevB.73.233305 PACS numbers: 78.67.De, 32.80.-t, 42.50.Gy, 42.50.Hz In the past decade several quantum optical coherence and interference effects 1,2 have been studied theoretically and ex- perimentally in intersubband transitions ISBTsin the con- duction band of semiconductor quantum wells QWs. Some of these phenomena are tunneling induced transparency, 3,4 electromagnetically induced transparency, 5–7 pulsed-induced quantum interference, 8 Autler-Townes splitting, 9 gain with- out inversion, 10–13 enhanced second harmonic generation, 14,15 enhanced index of refraction without absorption, 16 coherently induced one-dimensional photonic band gaps, 17 and coherent population trapping. 18 In addition, extremely useful devices such as ultrafast optical switches, 19–21 quantum switches, 22 and sensitive infrared detectors 23 are based on quantum optical coherence and in- terference effects in ISBTs in QWs. Furthermore, the relative phase of applied laser fields has been widely used for the coherent control of several impor- tant processes in atomic, molecular, and solid-state systems. 24 This method is usually termed as phase control. Phase control has already been applied for the coherent ma- nipulation of coherent population trapping, 25 coherent popu- lation transfer, 26 and electromagnetically induced transparency 27,28 in a closed-loop four-level atomic system. Also, the simultaneous excitation of a two-level atom by a fundamental laser field and its third harmonic can also lead to the phase control of light propagation in this medium. 29 In the area of semiconductors intensive interest has been given to the control of photocurrent directionality by simultaneous excitation of the semiconductors by a fundamental laser field and its second harmonic. 30–34 In the present brief report, we study phase control of an asymmetric semiconductor quantum well by simultaneous application of a laser field and its second harmonic. We con- sider an asymmetric quantum well structure with three en- ergy levels that forms the well-known “cascade” configura- tion, where all possible transitions are dipole allowed, see Fig. 1. The energy differences of the |1-|2and |2-|3 transitions are taken to be equal. Such structures have been already studied for quantum interference and gain, 12 for con- trolled coherent population trapping, 18 and for efficient sec- ond harmonic generation. 35,36 Actually, this system can be realized experimentally with only one laser frequency such as that derived from a CO 2 laser. The fundamental CO 2 laser frequency drives both the |1-|2and |2-|3transitions si- multaneously and the |1-|3transition is coupled by the second harmonic frequency of the CO 2 laser, achieved by frequency doubling in an appropriate infrared nonlinear crys- tal, such as, for example, AgGaS 2 , AgGaSe 2 , GaSe, and ZnGeP 2 . 37 The phase difference between the fundamental la- ser field and its second harmonic is externally altered. The small signal absorption or gainand dispersion spectra of a weak probe propagating through such a quantum well struc- ture are computed and are found to be crucially phase depen- dent; therefore it can be phase controlled. The structure un- der study combines simultaneously a closed-loop phase control system and a two-color “fundamental plus the second harmonic” phase control system. We consider a n-doped three-level asymmetric quantum well along the z direction with three equidistant dipole- allowed conduction band ISBTs as depicted in Fig. 1. The electron sheet density of the quantum well structure is such FIG. 1. aSchematic of the energy level arrangement for the asymmetric quantum wells considered in this paper. Subband levels are labeled in ascending energy: |1, |2, and |3. There are three possible optical transitions frequencies: |1|2 21 , |2|3 32 , and |1|3 31 . We take 21 = 32 = 31 / 2. The tran- sitions |1|2and |2|3are driven by a coupling field with optical frequency and the transition |1|3is coupled by a field with optical frequency 2. bSchematic of the asymmetric conduction band barrier arrangement to create the appropriate asymmetric quantum well structure. PHYSICAL REVIEW B 73, 233305 2006 1098-0121/2006/7323/2333054©2006 The American Physical Society 233305-1