Hindawi Publishing Corporation
Journal of Nanomaterials
Volume 2012, Article ID 193734, 2 pages
doi:10.1155/2012/193734
Editorial
Bulk Nanostructured Metals and Alloys:
Processing, Structure, and Thermal Stability
Hamed Bahmanpour,
1
Amir Kajbafvala,
2
Mohammad H. Maneshian,
3
Hamid Reza Zargar,
4
and Khaled Youssef
2
1
Department of Chemical Engineering and Materials Science, University of California, Davis, CA 95616, USA
2
Department of Materials Science and Engineering, North Carolina State University, Raleigh, NC 27695-7907, USA
3
Department of Materials Science and Engineering, University of North Texas, Denton, TX 76203, USA
4
Department of Metals and Materials Engineering, University of British Columbia, Vancouver, BC, Canada V6T 1Z4
Correspondence should be addressed to Hamed Bahmanpour, hbahman@ncsu.edu
Received 21 October 2012; Accepted 21 October 2012
Copyright © 2012 Hamed Bahmanpour et al. This is an open access article distributed under the Creative Commons Attribution
License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly
cited.
Nanostructured metals and alloys have been the focus of
research during the past few decades due to their inter-
esting microstructures and promising mechanical proper-
ties. Despite the fact that this class of materials shows
intriguing properties, there are roadblocks that prevent
large-scale production and industrial application of these
materials that include but not limited to low ductility and
poor thermal stability. In this regard, tailoring mechanical
and microstructural properties by developing new alloys
and inducing different microstructural features via various
processing routes have been the major point of interest
for researchers to overcome the difficulties in industri-
alization of nanomaterials. High tendency of nanograins
to reduce their energy by grain coalescence and growth
brings the thermodynamics and kinetics of grain growth
to attention in order to understand the phenomena and
develop thermally stable nanostructures. Attempts in this
regard include reducing the mobility of a grain boundary
by means of mechanisms such as solute drag, second-phase
particle pinning, and chemical ordering. On the other hand,
the demand for producing large-sized bulk parts, especially
in structural applications, has led to the emergence of
new processing techniques and further application-based
approaches to the issue of the nanostructured metals and
alloys. This special issue addresses the different challenges
for up scaling the production of nanostructured metals and
alloys with emphasis on processing, microstructure, and
thermal stability. We would like to express our appreciation
to all authors in this special issue for their help and efforts
in addressing these current issues in the field. Furthermore,
thanks are extended to all reviewers for enhancing the quality
of these papers.
This special issue contains six papers related to synthesis
and characterization of nanostructured metals and alloys. In
“Thermal stability of neodymium aluminates high-k dielectric
deposited by liquid injection MOCVD using single-source
heterometallic alkoxide precursors,” P. Taechakumput et al.
studied the effects of high-temperature post deposition
annealing (PDA) on the properties of the NdAlO
x
thin
films, deposited by metalorganic chemical vapor deposition
(MOCVD) using single-source precursor. These NdAlO
x
thin films were shown to remain amorphous up to 50
◦
C
as indicated by XRD. No significant level of crystallinity
or movement of metal ions was evident after annealing at
950
◦
C as indicated by MEIS energy spectra. Good electrical
integrity was maintained even after 950
◦
C PDA showing
the extracted dielectric permittivity of 12, a low leakage
density of 7 × 10
−7
Acm
−2
at 2 MV cm
−1
, and a density of
interface states at flat band D
it
of 4.01 × 10
11
cm
−2
eV
−1
.
These features make the neodymium aluminate a potential
candidate for the dielectric replacement.
In their paper, Z. S. Hu et al. studied “Align Ag
nanorods via oxidation reduction growth using RF-sputtering ”
and demonstrated an oxidation reduction growth (ORG)
technique with mixed-gas sputtering to create Ag nanorod
arrays via oxide-assisted growth without any chemical solu-
tions or contamination from aqueous solution. The ORG
methodology is used to deposit an Ag buffer layer with