Vol.:(0123456789) 1 3
Journal of the Iranian Chemical Society
https://doi.org/10.1007/s13738-020-02069-9
ORIGINAL PAPER
Magnetite (Fe
3
O
4
) nanoparticles‑supported dodecylbenzenesulfonic
acid as a highly efcient and green heterogeneous
catalyst for the synthesis of substituted quinolines
and 1‑amidoalkyl‑2‑naphthol derivatives
Deepak Katheriya
1
· Nipun Patel
1
· Harsh Dadhania
2
· Abhishek Dadhania
1
Received: 14 June 2020 / Accepted: 18 September 2020
© Iranian Chemical Society 2020
Abstract
Magnetically retrievable, magnetite (Fe
3
O
4
) nanoparticles-supported dodecylbenzenesulfonic acid (DDBSA@MNP) was
synthesized and characterized through diferent analytical techniques such as TEM, XRD, FTIR, TGA, SEM, EDX and
VSM. The catalytic efciency of synthesized DDBSA@MNP was evaluated for the synthesis of substituted quinolines and
1-amidoalkyl-2-naphthols through one-pot condensation. The methodology provides a facile approach for the synthesis of
targeted compounds with excellent isolated yields. Additionally, the catalyst can be recovered through external magnet and
reused up to fve reaction cycles with prominent reactivity. The present approach ofers many advantages such as green and
mild reaction condition, facile catalyst recovery and excellent isolated yield of fnal products.
Graphic abstract
Keywords Magnetic nanoparticles · Heterogeneous catalyst · One-pot condensation · Friedlander reaction
Introduction
Homogeneous catalysts have been known for several years
due to their distinct features such as high activity and selec-
tivity [1–3]. Homogeneous nature of the catalyst renders all
catalytic sites available for the reactants and also provides
the stereo- and regioselectivity to the reaction [4]. How-
ever, homogeneous catalysts contribute not more than 15%
of the industrial processes as compared to its counterpart
heterogeneous catalysts [5]. The reason behind this trend is
difculties associated with their separation and reusability.
Electronic supplementary material The online version of this
article (https://doi.org/10.1007/s13738-020-02069-9) contains
supplementary material, which is available to authorized users.
* Abhishek Dadhania
abhishekdadhania.bt@charusat.ac.in
1
Department of Chemical Sciences, P. D. Patel Institute
of Applied Sciences, Charotar University of Science
and Technology (CHARUSAT), Changa, Gujarat 388421,
India
2
Department of Chemistry, Sardar Patel University,
Vallabh Vidyanagar 388120, Gujarat, India