1536 Microsc. Microanal. 26 (Suppl 2), 2020
doi:10.1017/S1431927620018437 © Microscopy Society of America 2020
Revealing Nanoscale Order and Strain in Lightweight FeMnAlC Steel Alloys with Atomic-resolution
STEM
Michael Xu, Abinash Kumar and James LeBeau
Massachusetts Institute of Technology, Cambridge, Massachusetts, United States
High-Mn Fe-Mn-Al-C steels are lightweight alloys that have been shown to exhibit relatively high strength in
addition to high ductility, properties unique with respect to those of many other classes of steels [1, 2]. One of
the mechanisms linked to enhanced strain-hardening and ductility is short-range order (SRO)-linked planar
glide [3]. As a result, there is much interest in characterizing the nanoscale ordering of alloys having these
enhanced mechanical properties [4]. Using conventional transmission electron microscopy, the nanoscale
structure of FeMnAlC alloys has recently been shown to be non-homogenous with ordered clusters in an
austenite matrix [5], yet, direct observation of these ordered regions and the local strain fields that influence
properties remain.
In this presentation, we will show that direct observation of short-range ordering in the Fe-28Mn-9Al-0.8C
lightweight steel is possible using HAADF STEM. To characterize the extent of ordering, we will highlight
the use of atom column intensity correlation analysis of the high SNR Revolving STEM images [4, 6]. For
example, Figure 1a shows a low-magnification LAADF STEM image of the FeMnAlC alloy in which a series
of dislocations is seen. First, in order to determine the presence of intrinsic ordering in the bulk, atomic-
resolution imaging and analysis is performed away from these defects. Figure 1b shows an atomic resolution
HAADF RevSTEM image, from which near neighbor atom column intensity ratios are calculated. As shown
in Figures 2a and 2b, intensity and correlation analysis, respectively, reveals regions of strongly correlated
order separated by anti-phase boundaries. These correlated atom column intensities point to the presence of an
ordered L12 structure composed of Fe/Mn and Al.
We will also demonstrate that 4D STEM imaging, coupled with drift-corrected annular dark field and
integrated differential phase contrast imaging (iDPC), offers new insights into the structure of FeMnAlC
lightweight steels. Using the aforementioned methods, we will discuss the effect of heat treatments on the
formation of local atomic ordering in these lightweight steels and the modulation of strain fields at and near
defects such as twin boundaries and dislocations (Figure 1a). Finally, we will compare our results with those
obtained by conventional TEM methods to provide a connection to the long-range microstructure in FeMnAlC
alloys [7].
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