Citation: Chopra, H.; Bibi, S.; Kumar,
S.; Khan, M.S.; Kumar, P.; Singh, I.
Preparation and Evaluation of
Chitosan/PVA Based Hydrogel Films
Loaded with Honey for Wound
Healing Application. Gels 2022, 8, 111.
https://doi.org/10.3390/
gels8020111
Academic Editor: Rajendran
JC Bose
Received: 15 December 2021
Accepted: 7 February 2022
Published: 11 February 2022
Publisher’s Note: MDPI stays neutral
with regard to jurisdictional claims in
published maps and institutional affil-
iations.
Copyright: © 2022 by the authors.
Licensee MDPI, Basel, Switzerland.
This article is an open access article
distributed under the terms and
conditions of the Creative Commons
Attribution (CC BY) license (https://
creativecommons.org/licenses/by/
4.0/).
gels
Article
Preparation and Evaluation of Chitosan/PVA Based Hydrogel
Films Loaded with Honey for Wound Healing Application
Hitesh Chopra
1
, Shabana Bibi
2,3
, Sandeep Kumar
4
, Muhammad Saad Khan
5
, Pradeep Kumar
6,
*
and Inderbir Singh
1,
*
1
Chitkara College of Pharmacy, Chitkara University, Rajpura 140401, Punjab, India;
chopraontheride@gmail.com
2
Yunnan Herbal Laboratory, College of Ecology and Environmental Sciences, Yunnan University,
Kunming 650091, China; shabana_bibi@ynu.edu.cn
3
The International Joint Research Center for Sustainable Utilization of Cordyceps Bioresources in China and
Southeast Asia, Yunnan University, Kunming 650091, China
4
College of Pharmacy, Amar Shaheed Baba Ajit Singh Jujhar Singh Memorial College,
Ropar 140111, Punjab, India; sandeep_pharm70@yahoo.com
5
Department of Biosciences, Faculty of Sciences, COMSATS University Islamabad, Sahiwal 57000, Pakistan;
saad.khan@cuisahiwal.edu.pk
6
Department of Pharmacy and Pharmacology, School of Therapeutic Sciences, Faculty of Health Sciences,
University of the Witwatersrand, Johannesburg 2193, South Africa
* Correspondence: pradeep.kumar@wits.ac.za (P.K.); inderbir.singh@chitkara.edu.in (I.S.)
Abstract: In the present study, chitosan/polyvinyl alcohol (PVA)-based honey hydrogel films were
developed for potential wound healing application. The hydrogel films were developed by a solvent-
casting method and were evaluated in terms of thickness, weight variation, folding endurance,
moisture content and moisture uptake. The water vapor transmission rate was found to range
between 1650.50 ± 35.86 and 2698.65 ± 76.29 g/m
2
/day. The tensile strength and elongation at break
were found to range between 4.74 ± 0.83 and 38.36 ± 5.39 N, and 30.58 ± 3.64 and 33.51 ± 2.47 mm,
respectively, indicating significant mechanical properties of the films. SEM images indicated smooth
surface morphology of the films. FTIR, DSC and in silico analysis were performed, which highlighted
the docking energies of the protein–ligand complex and binding interactions such as hydrogen
bonding, Pi–Pi bonding, and Pi–H bonding between the selected compounds and target proteins;
hence, we concluded, with the three best molecules (lumichrome, galagin and chitosan), that there
was wound healing potential. In vitro studies pointed toward a sustained release of honey from
the films. The antimicrobial performance of the films was investigated against Staphylococcus aureus.
Overall, the results signaled the potential application of chitosan/PVA based hydrogel films as
wound dressings. Furthermore, in vivo experiments may be required to evaluate the clinical efficacy
of honey-loaded chitosan/PVA hydrogel films in wound healing.
Keywords: hydrogel films; chitosan/PVA; honey; wound healing
1. Introduction
Every year numerous patients suffer from different types of skin epidermal damage
such as burns, ulcers, and other traumatic incidents leading to the development of acute
and/or chronic wounds [1]. Wound healing is a complex phenomenon that includes the
inflammation phase, proliferation phase and tissue remodeling phase. Traditional wound
dressings such as cotton wool and gauze still possess the largest part of the wound dressing
market. Polymeric wound dressings may include films, foams, hydrogels, hydrocolloids
and fibers [2].
Hydrogels are three-dimensional polymeric networks that are capable of absorbing
water without dissolving [3]. Hydrogels have been explored for significant applications in
wound healing, drug delivery, water purification, tissue engineering, scaffoldings, and 3D
Gels 2022, 8, 111. https://doi.org/10.3390/gels8020111 https://www.mdpi.com/journal/gels