Full Paper ______________________________________________ Thematic Section: Quantum-Chemical Research.
The Reference Object Identifier – ROI: jbc-02/19-60-11-106 Subsection: Organic Chemistry.
106 ________ © Butlerov Communications. 2019. Vol.60. No.11. _________ Kazan. The Republic of Tatarstan. Russia.
The Digital Object Identifier – DOI: 10.37952/ROI-jbc-01/19-60-11-106
Submitted on November 22, 2019.
Spectral and quantum chemical study of tautomeric and ion
transformations of 2-(2-(2-hydroxy-5-sulfamoylphenyl)-
hydrazono)-3-oxo-N-phenylbutanamide
© Anh Thi Ngoc Vu,
1,2+
Mikhail A. Ryabov,
1
Olga V. Kovalchukova ,
1,3
* and Dmitr y S. Gusar ov
3
1
Department of General Chemistry. Peoples' Friendship University of Russia (RUND University). Miklukho-
Maklaya St., 6. Moscow, 117198. Russia. Phone: +7 977 879 0668. E-mail: vuanh0000@gmail.com
2
Department of Pharmaceuticals. Buon Ma Thuot University. Ha Huy Tap St., 298.
Buon Ma Thuot. Daclak, 630000. Vietnam.
3
Department of Organic Chemistry. A.N. Kosygin Russian State University (Technology. Design. Art).
Sadovnicheskaya St., 33. P.1. Moscow, 115035. Russia.
___________________________________
*Supervising author;
+
Corresponding author
Keywords: quantum chemical calculations, 2-arylhydrazono-1,3-dicarbonyl compounds, tautomeric,
conformer and ionic forms.
Abstract
In this paper, using the method DFT/B3LYP of quantum chemical modeling, the stability of tautomeric,
conformer, and anionic forms of 2-(2-(2-hydroxy-5-sulfamoylphenyl) hydrazone-3-oxo-N-phenylbutanamide
(H
2
L) was studied and the geometric, electronic structure and bond lengths of molecules in various tautomeric
forms were determined. It was shown that the stability of tautomeric molecules H
2
L as anionic forms was
determined by the number of existing intermolecular hydrogen bonds (closing six-membered and five-
membered cycles). The most stable tautomeric and conformal forms of an organic molecule and its dianion
are proposed. The interatomic distances, angles, charges on atoms, IR and electronic absorption spectra of
tautomeric forms of the molecule and dianion (H
2
L and L
2-
) were calculated. In this work, we studied the
electronic absorption spectra in an aqueous-alcoholic solution and found that in an alkaline medium the
molecule transforms into the ionic form with a bathochromic shift of 47 nm, corresponding to the results of
the shift of the long-wavelength band electronic absorption spectra upon transition from the hydrazotautomer
(form a) to the dianion form (form b’’) at 92 nm obtained by TD-DFT. The calculated results for the distance
and angles between atoms are in good agreement with the experimental data of the molecule by X-ray
diffraction analysis. It was shown that the IR spectrum of the stable form appears two absorption bands in the
region of 1690 and 1655 cm
– 1
, which are attributed to stretching vibrations of carbonyl groups (C = O), bound
by a strong intramolecular hydrogen bond and the presence of the NH-hydrazone fragment of the
1
H NMR
spectrum confirmed the most stable for a neutral molecule is the hydrazone form.
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