458 https://oamjms.eu/index.php/mjms/index
Scientifc Foundation SPIROSKI, Skopje, Republic of Macedonia
Open Access Macedonian Journal of Medical Sciences. 2022 Mar 25; 10(E):458-464.
https://doi.org/10.3889/oamjms.2022.8126
eISSN: 1857-9655
Category: E - Public Health
Section: Public Health Disease Control
Novel Copolymer Cationic from Agroindustrial Waste using
Microwave
Prayudhy Yushananta
1,2
*, Mei Ahyanti
1
1
Department of Environmetal Health, Politeknik Kesehatan Kemenkes Tanjungkarang, Lampung. Indonesia;
2
Doctoral Program
of Environmental Science, Universitas Lampung, Lampung. Indonesia
Abstract
BACKGROUND: A cationic copolymer has been developed to substitute synthetic coagulants, resulting in decreased
pH, potential health problems, high costs, and large sludge volumes.
AIM: This study evaluated the potential of banana pith in several treatments as a natural coagulant to reduce
turbidity, COD, and color.
METHODS: The synthesis was carried out by inserting the cationic moiety of GTA into the starch backbone by microwave
radiation. The cationic performance was tested four times, with a factorial design based on dose (4 levels), stirring speed
(3 levels), and stirring time (3 levels). A two-way ANOVA test was applied to determine the efect of treatment.
RESULTS: The results showed that the cationic polymer could reduce turbidity (94.4%), COD (19.4%), and color
(87.5%). Although all variables showed a signifcant efect (p < 0.05), the use of 300 mg/L dose, stirring speed
(200 rpm), for 5 min showed the highest reduction efect.
CONCLUSIONS: Using GTA and microwaves, banana pith starch can be modifed into an efective cationic
copolymer for water and wastewater treatment.
Edited by: Sasho Stoleski
Citation: Yushananta P, Ahyanti M. Novel Copolymer
Cationic from Agroindustrial Waste using Microwave.
Open Access Maced J Med Sci. 2022 Mar 25; 10(E):458-464.
https://doi.org/10.3889/oamjms.2022.8126
Keywords: Coagulation-focculation; Banana pith;
Turbidity; COD; Color
*Correspondence: Prayudhy Yushananta, Department
of Environmetal Health, Politeknik Kesehatan Kemenkes
Tanjungkarang, Lampung, Indonesia.
E-mail: prayudhyyushananta@gmail.com
Received: 30-Nov-2021
Revised: 23-Feb-2022
Accepted: 24-Mar-2022
Copyright: © 2022 Prayudhy Yushananta, Mei Ahyanti
Funding: This research did not receive any fnancial support
Competing Interests: The authors have declared that no
competing interests exist
Open Access: This is an open-access article distributed
under the terms of the Creative Commons Attribution-
NonCommercial 4.0 International License (CC BY-NC 4.0)
Introduction
Water supply is intended to carry out their
activities as humans [1]. Two serious problems increase
the need for clean water, namely, population growth and
rapid industrialization growth [2], [3], [4], [5], [6], [7], [8]. It is
estimated that global water demand will increase to meet
the needs of 9.7 billion people by 2050, from 7.7 billion in
2020 [9]. In the industrial sector, clean water is needed to
reach about 22% of the total water available [10]. On the
water supply aspect, the problems are the increase in water
pollution from various toxic pollutants from industrial and
domestic [4], [5], [7], [11], [12], [13], [14], [15]. Domestic
wastewater mainly contains pathogenic microbiological,
such as Coliform, E. coli, Streptococcus sp.,
Pseudomonas sp., Vibrio sp., Clostridia sp., Arcobacter
sp., Thiobacillus sp. [16], [17]. Meanwhile, the industrial
wastewater is hydraulic overload, extreme temperatures,
oil and grease, acids or bases, suspended solids,
inorganic or organic, toxic and volatile materials, odors,
or corrosive gases [4], [5], [7], [11], [12], [13], [14], [15].
These two problems encourage massive
groundwater exploitation [15], [18]. Resulting in a reduced
volume of groundwater storage, land subsidence,
negative impacts on water supply, decreased surface
water fow and loss of springs, and loss of wetlands,
thus threatening to threaten the sustainability of water
supply [19], [20]. Globally, it estimated a reduction
in groundwater from 1900 to 2008 of 4.500 km
3
(the
equivalent of a sea-level rise of 12.6 mm). Since about
1950, the rate of groundwater reduction has increased
signifcantly, averaging about 145 km
3
/year (equivalent
to 0.40 mm/year of level increase) [19], [21].
Water treatment is the most rational choice to
solve the demand and supply of clean water problems,
in addition to eforts to diversify sustainable water
sources (including the use of rainwater and seawater
desalination) [1], [22]. Many technologies have been
developed to treat water and wastewater, such as
precipitation, adsorption, coagulation, fotation, ion
exchange, membrane fltration, and biological and
electrolytic methods have been used to remove particles
from water [23], [24], [25], [26], [27], [28], [29], [30],
[31], [32], [33], [34], [35], [36]. However, coagulation
and focculation techniques are the most widely applied
technology globally as a vital step in removing colloid
particles, natural organic matter, microorganisms, and
inorganic ions present in untreated water [15], [32],
[34], [37], [38], [39], [40].
A coagulant is an essential material in the
coagulation-focculation process which refers to the
agglomeration process of colloidal particles with an
average size of 5−200 nm and small suspended solids in
water infuenced by several factors such as temperature,
ionic strength, pH. type and dose of material, coagulant,