Heavy metals and trace
elements contamination risks in
peri-urban agricultural soils in
Nairobi city catchment, Kenya
Arcadius Martinien Agassin Ahogle
1,2
*
, Sammy Letema
1
,
Gertrud Schaab
3
, Veronica Ngure
4
, Abraham R. Mwesigye
5
and Nicholas K. Korir
6
1
Department of Spatial and Environmental Planning, Kenyatta University, Nairobi, Kenya,
2
Department of Soil Science, Faculty of Agronomic Sciences, University of Abomey-Calavi,
Abomey-calavi, Benin,
3
Faculty of Information Management and Media, Karlsruhe University of
Applied Sciences, Karlsruhe, Germany,
4
Department of Biological Sciences, Laikipia University,
Nyahururu, Kenya,
5
School of Forestry, Environment and Geographical Sciences, College of
Agriculture and Environmental Sciences, Makerere University-Kampala, Kampala, Uganda,
6
Department of Agricultural Science and Technology, Kenyatta University, Nairobi, Kenya
Introduction: With urbanization and industrialization in the developing world,
urban and peri-urban agriculture is increasingly contributing to urban food
systems, employment, and income generation opportunities. However,
urbanization and industrialization may release harmful pollutants, including
heavy metals and trace elements into agricultural soils, posing ecological,
environmental and public health concerns. This paper assessed the potential
risks of soil contamination with heavy metals and trace elements in peri-urban
farmlands in Nairobi city catchment in Kenya.
Methods: A total of 60 soil samples were collected from ten vegetable farming
zones (S1-S10) and processed following standard protocols. The
concentrations of As, Cd, Co, Cr, Cu, Fe, Hg, Mn, Ni, Pb, V and Zn were
analyzed in the samples using inductively coupled plasma-mass spectrometry
(ICP-MS).
Results and discussion: Results revealed that the soil samples have elevated
concentrations of As, Cd, Co, Cr, Cu, Fe, Hg, Mn, Ni, Pb, V and Zn, with some
elements including As (1.7%), Cd (13.3%), Mn (80%), Pb (1.7%) and Zn (11.7%)
exceeding the permissible thresholds for agricultural soils. The spatial
distribution of the elements exhibited three similar distribution patterns with
slight variations between the hotspot sites of the different elements: (i) Co and
Mn, (ii) Cu and Cr and (iii) As, Cd, Fe, Hg, Pb and Zn, while Ni and V exhibited
singular spatial distributions compared to other elements. Elements such as As,
Cd, Co, Fe, Hg, Mn, Pb and Zn appeared to be of anthropogenic enrichment,
Frontiers in Soil Science frontiersin.org 01
OPEN ACCESS
EDITED BY
Christos Damalas,
Democritus University of Thrace,
Greece
REVIEWED BY
Chengyu Xie,
Xiangtan University, China
Hansong Chen,
Zhejiang Normal University, China
Fathy Elbehiry,
Kafrelsheikh University, Egypt
*CORRESPONDENCE
Arcadius Martinien Agassin Ahogle
ahoglearcadius@gmail.com
SPECIALTY SECTION
This article was submitted to
Soil Pollution & Remediation,
a section of the journal
Frontiers in Soil Science
RECEIVED 19 September 2022
ACCEPTED 12 December 2022
PUBLISHED 12 January 2023
CITATION
Ahogle AMA, Letema S, Schaab G,
Ngure V, Mwesigye AR and Korir NK
(2023) Heavy metals and trace
elements contamination risks in peri-
urban agricultural soils in Nairobi city
catchment, Kenya.
Front. Soil Sci. 2:1048057.
doi: 10.3389/fsoil.2022.1048057
COPYRIGHT
© 2023 Ahogle, Letema, Schaab, Ngure,
Mwesigye and Korir. This is an open-
access article distributed under the
terms of the Creative Commons
Attribution License (CC BY). The use,
distribution or reproduction in other
forums is permitted, provided the
original author(s) and the copyright
owner(s) are credited and that the
original publication in this journal is
cited, in accordance with accepted
academic practice. No use,
distribution or reproduction is
permitted which does not comply with
these terms.
TYPE Original Research
PUBLISHED 12 January 2023
DOI 10.3389/fsoil.2022.1048057