Radiation Detection Technology and Methods (2018) 2:44
https://doi.org/10.1007/s41605-018-0075-x
ORIGINAL PAPER
Investigation of modified zinc borate glasses doped with BaO
as a nuclear radiation-shielding material
H. A. Saudi
1
· S. U. El-Kameesy
2
Received: 22 April 2018 / Revised: 13 August 2018 / Accepted: 14 August 2018
© Institute of High Energy Physics, Chinese Academy of Sciences; Nuclear Electronics and Nuclear Detection Society and Springer Nature Singapore Pte
Ltd. 2018
Abstract
Background Radiation protection and detection have been a main interest for researchers. The prepared glass samples were
subjected to experimental investigations to evaluate their mechanical and attenuation properties. As a consequence, the values
of the mass attenuation coefficient, total electronic cross section, the effective atomic number and an effective electron number
were determined and utilized to assess the shielding effectiveness of the investigated glass samples. The mass attenuation
coefficients of these samples were calculated theoretically using WinXcom program.
Purpose Preparation of glass of borate with zinc and barium can withstand shock, heat and corrosion to be used as a radiation
shield.
Methods Glass samples were prepared by melt quenching technique. Density and molar volume measurements were obtained
by applying the Archimedes principle. The hardness was measured by using a microhardness tester (Leco AMH 100, USA)
for sample indentation. The thermal behavior of the glass samples was investigated by differential scanning calorimetry
(DSC). Also, by using a scintillator detector (1.5
′′
× 1.5
′′
NaI (Tl)) exposed to
232
Th,
137
Cs and
60
Co gamma ray sources
with accuracy range 0.12%.
Results The investigated glasses have relatively good gamma ray attenuation properties, water resistance ability and thermal
stability with increasing barium oxide. So, they can be used in containers for keeping radioactive waste and radioactive
sources.
Conclusion The changes in the molar volume and density show approximately opposite linear trends. Also, μm is dependent
on the chemical compositions of glass samples and energy of gamma rays. Good agreement between the experimentally
obtained mass attenuation coefficient values and the corresponding theoretical predictions based on the known WinXcom
program was observed. Additionally, the effect of gamma irradiation on this glass is minor because its impact on the hardness
values and dissolution rate is extremely small.
Keywords Borate glasses · Shielding properties · Hardness · Durability
Introduction
Today, developing materials which might be employed in
the environment of high radiation exposure has become one
among the foremost vital analysis areas. These materials
will play a good role in industrial, medical, engineering
B H. A. Saudi
heba_saudi@hotmail.com; heba_saudi@azhar.edu.eg
1
Department of Physics, Faculty of Science (Girls’ Branch),
Al-Azhar University, Cairo, Egypt
2
Department of Physics, Faculty of Science, Ain Shams
University, Cairo, Egypt
and lots of different scientific applications. There is invari-
ably a requirement to develop material, which might be used
under laborious conditions of nuclear radiation exposure and
may act as a shielding material. Additions of high-atomic-
number components with the acknowledged quantitative
relation of the amorphous mixture fashioned glass produce
an honest shielding properties material. Glassy materials,
which might be modified through their chemical composi-
tion additionally to their high optical transmission, became
appropriate to be used as shielding materials for nuclear radi-
ation [1]. Borate glass may be a form of glass with the most
glass-forming constituent that is an elemental chemical com-
pound that is one among the foremost vital glass formers
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