Original Article Reduction of Diabetes-Induced Oxidative Stress, Fibrotic Cytokine Expression, and Renal Dysfunction in Protein Kinase C–Null Mice Yuzuru Ohshiro, 1 Ronald C. Ma, 1 Yutaka Yasuda, 1 Junko Hiraoka-Yamamoto, 1 Allen C. Clermont, 1 Keiji Isshiki, 1 Kunimasa Yagi, 1 Emi Arikawa, 1 Timothy S. Kern, 2 and George L. King 1 Diabetes induces the activation of several protein kinase C (PKC) isoforms in the renal glomeruli. We used PKC- / mice to examine the action of PKC-isoforms in diabetes- induced oxidative stress and renal injury at 8 and 24 weeks of disease. Diabetes increased PKC activity in renal cortex of wild-type mice and was significantly reduced (<50% of wild-type) in diabetic PKC- / mice. In wild-type mice, diabetes increased the translocation of PKC-and -1 to the membrane, whereas only PKC-was elevated in PKC- / mice. Increases in urinary isoprostane and 8-hydroxydeoxyguanosine, parameters of oxidative stress, in diabetic PKC- / mice were significantly reduced com- pared with diabetic wild-type mice. Diabetes increased NADPH oxidase activity and the expressions of p47 phox , Nox2, and Nox4 mRNA levels in the renal cortex and were unchanged in diabetic PKC- / mice. Increased expres- sion of endothelin-1 (ET-1), vascular endothelial growth factor (VEGF), transforming growth factor (TGF)-, con- nective tissue growth factor (CTGF), and collagens IV and VI found in diabetic wild-type mice was attenuated in diabetic PKC- / mice. Diabetic PKC- / mice were pro- tected from renal hypertrophy, glomerular enlargement, and hyperfiltration observed in diabetic wild-type mice and had less proteinuria. Lack of PKC-can protect against diabetes-induced renal dysfunction, fibrosis, and increased expressions of Nox2 and -4, ET-1, VEGF, TGF-, CTGF, and oxidant production. Diabetes 55:3112–3120, 2006 D iabetic nephropathy is characterized by glomer- ular hyperfiltration, extracellular matrix accu- mulation, glomerular enlargement, mesangial expansion, and intertubular fibrosis, resulting ultimately in diabetic glomerulosclerosis and progressive renal insufficiency (1,2). Hyperglycemia-induced meta- bolic and hemodynamic factors are thought to be media- tors of this injury, which is associated with the diabetic state (3). The hemodynamic factors implicated in the pathogenesis of diabetic nephropathy include increased systemic and intraglomerular pressure and activation of various vasoactive hormone pathways including the renin- angiotensin system and endothelins (3). This may interact with metabolic pathways activating signaling pathways that lead to renal injury. Multiple biochemical path- ways have been proposed to explain the adverse effects of hyperglycemia. Activation of diacylglycerol (DAG)– protein kinase C (PKC) pathway (4), enhanced polyol path- way (5), increased oxidative stress (6), and overproduction of advanced glycation end products (AGEs) (7) have all been proposed as potential cellular mechanisms by which hyper- glycemia induces chronic diabetes complications. We and others (8 –10) have previously reported that multiple PKC isoforms are activated in each vascular tissue of diabetic animal models, and activation of the DAG-PKC pathway is a key mediator of diabetes vascular complications. Immunoblotting studies have reported that PKC-and -1 isoforms were increased in vivo in mem- branous fractions (activated pool) of diabetic rat glomeruli and in vitro in mesangial cells exposed to elevated glucose levels (10), whereas PKC-2 was reported to be preferen- tially activated in the aorta and heart of diabetic rats (8). Whiteside and Dlugosz (11) reported that PKC-and - isoforms were also increased in the membrane pool in the glomeruli of diabetic rats. Treatment of diabetic animals with a selective PKC-isoform inhibitor (LY333531 or ruboxistaurin [RBX]) was associated with normalization of hemodynamic changes, extracellular matrix, and histo- logical features of glomerular damage in animal models of diabetes (10,12,13). Phase two clinical trial results sug- gested that RBX can decrease the loss of glomerular filtration rate (GFR) and proteinuria in diabetic patients already treated with inhibitors of angiotensin actions (14). Recently, activation of NADPH oxidase and increased reactive oxygen species (ROS) production have been proposed as important mediators of renal dysfuncton in diabetes (15,16). We have reported that inhibition of PKC-by RBX can also normalize diabetes or hyperglyce- mia-induced oxidative stress (17). PKC-has been noted to contribute to NADPH oxidase activations in multiple cells, including endothelial and mesangial cells (18). How- ever, it is still unclear which of the renal abnormalities are induced by PKC-isoforms as compared with other PKC isoforms and which of the potential downstream biochem- From the 1 Joslin Diabetes Center, Harvard Medical School, Boston, Massa- chusetts; and the 2 Department of Medicine, Case Western Reserve University, Cleveland, Ohio. Address correspondence and reprint requests to George L. King, Research Director, Joslin Diabetes Center, One Joslin Place, Boston, MA 02215. E-mail: george.king@joslin.harvard.edu. Received for publication 30 June 2006 and accepted in revised form 11 August 2006. Y.O., R.C.M., and Y.Y. contributed equally to this work. 8-OHdG, 8-hydroxydeoxyguanosine; AGE, advanced glycation end product; CTGF, connective tissue growth factor; DAG, diacylglycerol; ET-1, endothe- lin-1; FF, filtration fraction; GFR, glomerular filtration rate; PAH, para- aminohippurate; PKC, protein kinase C; RBX, ruboxistaurin; ROS, reactive oxygen species; RPF, renal plasma flow; TGF, transforming growth factor; VEGF, vascular endothelial growth factor. DOI: 10.2337/db06-0895 © 2006 by the American Diabetes Association. The costs of publication of this article were defrayed in part by the payment of page charges. This article must therefore be hereby marked “advertisement” in accordance with 18 U.S.C. Section 1734 solely to indicate this fact. 3112 DIABETES, VOL. 55, NOVEMBER 2006