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International Journal of Thermal Sciences
journal homepage: www.elsevier.com/locate/ijts
Entry length convective heat transfer in a monolith: The effect of upstream
turbulence
Ivan Cornejo
a,b
, Gonzalo Cornejo
b
, Petr Nikrityuk
a
, Robert E. Hayes
a,*
a
Department of Chemical and Materials Engineering, University of Alberta, Edmonton, Canada
b
Departamento de Ingenieria Quimica y Ambiental, Universidad Tecnica Federico Santa Maria, Valparaiso, Chile
ARTICLE INFO
Keywords:
Monolith
Channels
Turbulence
Nusselt
CFD
Catalytic converter
ABSTRACT
In a typical practical monolith reactor implementation, turbulent flow in a large pipe or inlet header enters small
monolith channels. After some distance the flow becomes fully developed laminar flow. It has been shown that
the distance over which the turbulence transitions to laminar flow is significant. This paper reports results of
investigation into the value of the Nusselt number in the entry region of a circular tube under conditions of
decaying turbulence. Large Eddy Simulations (LES) are used to model the flow. LES simulations show that the
Nusselt number is significantly larger in the entry region compared to the classical case of developing laminar
flow. The entry length Nu number depends not only on the inverse Graetz number, but also independently on the
Reynolds number, turbulence length scale and upstream turbulence intensity. A general correlation is developed
that relates the Nu number in the entry region to the inverse Graetz number, Reynolds number, inlet turbulence
intensity and turbulence length scale.
1. Introduction
Monolith reactors are extensively used in the automotive industry as
catalytic converters. A typical converter consists of a metallic carcass
containing the monolith, an inlet diffuser, and an outlet cone, as shown
in Fig. 1. To add catalyst metals, such as platinum, palladium or rho-
dium, a coating process is performed which results in a thin layer of
washcoat fixed to the inner walls of the channels of the monolith, where
the chemical reactions occur.
In automotive applications the converter is fed with the exhaust
from the engine, which is fully turbulent in the exhaust pipe with a
Reynolds number (Re) of the order of 10
4
. Due to the size of the
monolith channels, the Re decreases by orders of magnitude inside
them, down to sub-critical values. Based on that, the flow in the
channels is often assumed to be fully laminar along the entire substrate.
In reality, at the diffuser-monolith interface the turbulence in the dif-
fuser collides with the walls of the monolith and it is forced into the
channels, producing an acceleration due to the reduction of the open
frontal area [1,2]. Vortices larger than the cross-section of the channels
break into smaller ones and enter the substrate. Despite the low Re, the
turbulence does not disappear spontaneously; it decreases at a rate
dominated by the Re, in some cases over a distance that covers a sig-
nificant portion of the channel. The magnitude of the effect of such
turbulence on the key variables of the converter, such as the pressure
drop, and heat and mass transfer inside the substrate, is still a matter of
discussion among the community. The performance of the reactor, and
the fuel efficiency of the engine, ultimately relies on the design of the
substrate and the catalyst, making an accurate description of the phe-
nomena inside of the channels important. The motivation of this paper
is to build an understanding of the effect of the turbulence entering the
monolith and to quantify the magnitude of its impact on the effective
heat and mass transfer coefficients between the fluid and the channel
walls.
In typical catalytic converters, the monolith is made from ceramic
and contains thousands of parallel channels. Since the hydraulic dia-
meter of the channels is of the order of one millimetre, it is very difficult
to measure local profiles of velocity or temperature inside the substrate
without affecting them. Even when it is possible to make measure-
ments, it is done at the expense of the accuracy of the result [3]. Re-
action rate constants have an exponential dependence on the tem-
perature, which is often higher close to the entrance of the channels
during normal operation. It is precisely there where the turbulence
plays a role as well, reinforcing the motivation of this study.
The main focus is the evaluation of the convective heat transfer
coefficient along the channels, and to make a comparison of the Nusselt
(Nu) with and without turbulence entering the channels. Turbulence is
characterised by the presence of a series of vortices of several sizes that
improve significantly the transport of momentum, heat and mass. Since
https://doi.org/10.1016/j.ijthermalsci.2018.12.044
Received 16 August 2018; Received in revised form 28 November 2018; Accepted 28 December 2018
*
Corresponding author.
E-mail address: hayes@ualberta.ca (R.E. Hayes).
International Journal of Thermal Sciences 138 (2019) 235–246
1290-0729/ © 2018 Published by Elsevier Masson SAS.
T